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Torsion of a square section bar Example of torsion mechanics. In the field of solid mechanics, torsion is the twisting of an object due to an applied torque [1] [2].Torsion could be defined as strain [3] [4] or angular deformation [5], and is measured by the angle a chosen section is rotated from its equilibrium position [6].
where J is the 3 J coupling constant, is the dihedral angle, and A, B, and C are empirically derived parameters whose values depend on the atoms and substituents involved. [3] The relationship may be expressed in a variety of equivalent ways e.g. involving cos 2φ rather than cos 2 φ —these lead to different numerical values of A , B , and C ...
Molecular geometries can be specified in terms of 'bond lengths', 'bond angles' and 'torsional angles'. The bond length is defined to be the average distance between the nuclei of two atoms bonded together in any given molecule. A bond angle is the angle formed between three atoms across at least two bonds.
In biochemistry, a Ramachandran plot (also known as a Rama plot, a Ramachandran diagram or a [φ,ψ] plot), originally developed in 1963 by G. N. Ramachandran, C. Ramakrishnan, and V. Sasisekharan, [1] is a way to visualize energetically allowed regions for backbone dihedral angles ( also called as torsional angles , phi and psi angles ) ψ ...
In proteins there are four major torsion angles of interest: phi, psi, omega and chi-1. Traditionally protein NMR spectroscopists have used vicinal J-coupling information and the Karplus relation to determine approximate backbone torsion angle constraints for phi and chi-1 angles. [3] However, several studies in the early 1990s pointed out the ...
Geometric relevance: The torsion τ(s) measures the turnaround of the binormal vector. The larger the torsion is, the faster the binormal vector rotates around the axis given by the tangent vector (see graphical illustrations). In the animated figure the rotation of the binormal vector is clearly visible at the peaks of the torsion function.
The torsion constant or torsion coefficient is a geometrical property of a bar's cross-section. It is involved in the relationship between angle of twist and applied torque along the axis of the bar, for a homogeneous linear elastic bar. The torsion constant, together with material properties and length, describes a bar's torsional stiffness.
Free energy diagram of n-butane as a function of dihedral angle. In stereochemistry, a torsion angle is defined as a particular example of a dihedral angle, describing the geometric relation of two parts of a molecule joined by a chemical bond. [4] [5] Every set of three non-colinear atoms of a molecule defines a half-plane. As explained above ...