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The high temperature of annealing may result in oxidation of the metal's surface, resulting in scale. If scale must be avoided, annealing is carried out in a special atmosphere, such as with endothermic gas (a mixture of carbon monoxide, hydrogen gas, and nitrogen gas). Annealing is also done in forming gas, a mixture of hydrogen and nitrogen.
This produces steel that is much stronger than full-annealed steel, and much tougher than tempered quenched steel. However, added toughness is sometimes needed at a reduction in strength. Tempering provides a way to carefully decrease the hardness of the steel, thereby increasing the toughness to a more desirable point.
If a disordered state is not in thermodynamic equilibrium, one speaks of quenched disorder. For instance, a glass is obtained by quenching (supercooling) a liquid. By extension, other quenched states are called spin glass, orientational glass. In some contexts, the opposite of quenched disorder is annealed disorder.
However, quenching certain steel too fast can result in cracking, which is why high-tensile steels such as AISI 4140 should be quenched in oil, tool steels such as ISO 1.2767 or H13 hot work tool steel should be quenched in forced air, and low alloy or medium-tensile steels such as XK1320 or AISI 1040 should be quenched in brine.
This is the most common state for finished articles such as tools and machine parts. In contrast, the same steel composition in annealed state is softer, as required for forming and machining. Depending on the temperature and composition of the steel, it can be hardened or softened. To make steel harder, it must be heated to very high temperatures.
The earliest examples of quenched steel may come from ancient Mesopotamia, with a relatively secure example of a fourth-century BC quench-hardened chisel from Al Mina in Turkey. [6] Book 9, lines 389-94 of Homer's Odyssey is widely cited as an early, possibly the first, written reference to quenching: [ 3 ] [ 7 ]
This causes carbon to diffuse into the surface of the steel. The depth of this high carbon layer depends on the exposure time, but 0.5mm is a typical case depth. Once this has been done the steel must be heated and quenched to harden this higher carbon 'skin'. Below this skin, the steel core will remain soft due to its low carbon content.
This process is often used for knife making, by heating only the edge of a previously quenched and tempered blade. When edge turns the proper color temperature, it is quenched, hardening only the edge, but leaving most of the rest of the blade at the lower hardness. The knife is then tempered again to produce the final differential hardness. [16]
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