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Chemical reactions are determined by the laws of thermodynamics. Reactions can proceed by themselves if they are exergonic, that is if they release free energy. The associated free energy change of the reaction is composed of the changes of two different thermodynamic quantities, enthalpy and entropy: [17]
Chemical potential has units of joules per mole (J/mol), or energy per amount of matter. Chemical potential can be used to characterize the specific Gibbs free energy changes occurring in chemical reactions or other transformations. Formulae involving activities can be simplified by considering that: For a chemical solution:
The reaction products of the combustion of methane are carbon dioxide and water. Products are the species formed from chemical reactions. [1] During a chemical reaction, reactants are transformed into products after passing through a high energy transition state. This process results in the consumption of the reactants.
Thus, it can be said that the reactions involving dramatic changes in position of nuclei actually occur through a series of simple chemical reactions. Hammond postulate is another tool which assists in drawing the energy of a transition state relative to a reactant, an intermediate or a product. It states that the transition state resembles the ...
The total free energy change of a reaction is independent of the activation energy however. Physical and chemical reactions can be either exergonic or endergonic, but the activation energy is not related to the spontaneity of a reaction. The overall reaction energy change is not altered by the activation energy.
Hess's law states that the change of enthalpy in a chemical reaction is the same regardless of whether the reaction takes place in one step or several steps, provided the initial and final states of the reactants and products are the same. Enthalpy is an extensive property, meaning that its value is proportional to the system size. [4]
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