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An overview of absorption of electromagnetic radiation.This example shows the general principle using visible light as a specific example. A white light source—emitting light of multiple wavelengths—is focused on a sample (the pairs of complementary colors are indicated by the yellow dotted lines).
An overview of electromagnetic radiation absorption. This example discusses the general principle using visible light.A white beam source – emitting light of multiple wavelengths – is focused on a sample (the complementary color pairs are indicated by the yellow dotted lines).
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
The absorption of electromagnetic radiation by water depends on the state of the water. The absorption in the gas phase occurs in three regions of the spectrum. Rotational transitions are responsible for absorption in the microwave and far-infrared , vibrational transitions in the mid-infrared and near-infrared .
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments. [1]
Absorbance is defined as "the logarithm of the ratio of incident to transmitted radiant power through a sample (excluding the effects on cell walls)". [1] Alternatively, for samples which scatter light, absorbance may be defined as "the negative logarithm of one minus absorptance, as measured on a uniform sample". [2]
Common examples include retinal (used in the eye to detect light), various food colorings, fabric dyes (azo compounds), pH indicators, lycopene, β-carotene, and anthocyanins. Various factors in a chromophore's structure go into determining at what wavelength region in a spectrum the chromophore will absorb.
For example, white paint is quoted as having an absorptivity of 0.16, while having an emissivity of 0.93. [13] This is because the absorptivity is averaged with weighting for the solar spectrum, while the emissivity is weighted for the emission of the paint itself at normal ambient temperatures.