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Oleum (Latin oleum, meaning oil), or fuming sulfuric acid, is a term referring to solutions of various compositions of sulfur trioxide in sulfuric acid, or sometimes more specifically to disulfuric acid (also known as pyrosulfuric acid). [1] Oleums can be described by the formula ySO 3 ·H 2 O where y is the
The Parikh–Doering oxidation is an oxidation reaction that transforms primary and secondary alcohols into aldehydes and ketones, respectively. [1] The procedure uses dimethyl sulfoxide (DMSO) as the oxidant and the solvent, activated by the sulfur trioxide pyridine complex (SO 3 •C 5 H 5 N) in the presence of triethylamine or diisopropylethylamine as base.
Sulfur trioxide is a reagent in sulfonation reactions. Dimethyl sulfate is produced commercially by the reaction of dimethyl ether with sulfur trioxide: [20] CH 3 OCH 3 + SO 3 → (CH 3) 2 SO 4. Sulfate esters are used as detergents, dyes, and pharmaceuticals. Sulfur trioxide is generated in situ from sulfuric acid or is used as a solution in ...
Sulfur is released from the salt and diffuses into the metal substrate, forming grey- or blue-colored aluminum or chromium sulfides. With the aluminum or chromium sequestered, after the salt layer has been removed, the steel cannot rebuild a new protective oxide layer. Alkali sulfates are formed from sulfur trioxide and sodium-containing ...
Sulfur trioxide is the active ingredient in many sulfonation reactions. Typical conditions involve heating the aromatic compound with sulfuric acid: [2] C 6 H 6 + H 2 SO 4 → C 6 H 5 SO 3 H + H 2 O. Sulfur trioxide or its protonated derivative is the actual electrophile in this electrophilic aromatic substitution.
Sulfur trioxide, SO 3, a chemical compound of sulfur and the anhydride of sulfuric acid; Sulfite, SO 2− 3, a chemical ion composed of sulfur and oxygen with a 2− charge; SO(3), the special orthogonal group in 3 dimensions; the rotations that can be given an object in 3-space; Star Ocean: Till the End of Time, the third main game in the Star ...
The addition of at least 2 equivalents of base — typically triethylamine — will deprotonate the alkoxysulfonium ion to give the sulfur ylide 7. In a five-membered ring transition state, the sulfur ylide 7 decomposes to give dimethyl sulfide and the desired carbonyl compound 8. The mechanism of the Swern oxidation.
Sulfamic acid is produced industrially by treating urea with a mixture of sulfur trioxide and sulfuric acid (or oleum). The conversion is conducted in two stages, the first being sulfamation: OC(NH 2) 2 + SO 3 → OC(NH 2)(NHSO 3 H) OC(NH 2)(NHSO 3 H) + H 2 SO 4 → CO 2 + 2 H 3 NSO 3. In this way, approximately 96,000 tonnes were produced in ...