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A non-physical standard state is one whose properties are obtained by extrapolation from a physical state (for example, a solid superheated above the normal melting point, or an ideal gas at a condition where the real gas is non-ideal). Metastable liquids and solids are important because some substances can persist and be used in that state ...
Inert atmospheres consisting of gases such as argon, nitrogen, or helium are commonly used in chemical reaction chambers and in storage containers for oxygen-or water-sensitive substances, to prevent unwanted reactions of these substances with oxygen or water. [4] Argon is widely used in fluorescence tubes and low energy light bulbs.
Some constants, such as the ideal gas constant, R, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as K f (the freezing point depression constant, or cryoscopic constant ), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore ...
The following list has substances known to be gases, but with an unknown boiling point. Fluoroamine; Trifluoromethyl trifluoroethyl trioxide CF 3 OOOCF 2 CF 3 boils between 10 and 20° [142] Bis-trifluoromethyl carbonate boils between −10 and +10° [37] possibly +12, freezing −60° [143]
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
Gas stoichiometry deals with reactions involving gases, where the gases are at a known temperature, pressure, and volume and can be assumed to be ideal gases. For gases, the volume ratio is ideally the same by the ideal gas law , but the mass ratio of a single reaction has to be calculated from the molecular masses of the reactants and products.
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In a gas, the molecules have enough kinetic energy so that the effect of intermolecular forces is small (or zero for an ideal gas), and the typical distance between neighboring molecules is much greater than the molecular size. A gas has no definite shape or volume, but occupies the entire container in which it is confined.