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An important synthetic application using such dialkylboranes, such as diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. [9] [10] Some diaryl and dialkylboranes are well known. Dimesitylborane is a dimer (C 6 H 2 Me 3) 4 B 2 H 2). It reacts only slowly with simple terminal alkenes.
Unlike silicates, boron minerals never contain boron with coordination number greater than four. A typical motif is exemplified by the tetraborate anions of the common mineral borax, shown at left. The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na +) in borax. [1]
Borate glasses also have major differences in their optical properties. [ 2 ] The single largest use of boron compounds in the world (accounting for half of total global use) is the production of certain types of boron-treated glass fiber for insulating and structural fiberglass . [ 3 ]
Trimethyl borate is the organoboron compound with the formula B(OCH 3) 3 and a metal alkoxide. It is a colourless liquid that burns with a green flame. [1] It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method). [2]
Applications [ edit ] The tetrapropylboranuide anion is a reagent for the propylation of organometallic compounds, including organotin , organomercury , and organolead compounds of interest to environmental and public health research. [ 4 ]
This makes it an excellent candidate to be used in tissue engineering applications. Although this material is known to be brittle, it is still used extensively to enhance the growth of bone since new forms of bioactive glasses are based on borate and borosilicate compositions.
Lithium metaborate forms glass relatively easily, and consists of approximately 40% tetrahedral borate anions, and 60% trigonal planar boron. The ratio of tetrahedral to trigonal boron has been shown to be strongly temperature dependent in the liquid and supercooled liquid state. [3] [4]
While boric acid itself does kill self-grooming insects if ingested, it must be presented to an insect in both sufficient concentration and in an ingestible form in order to achieve insect fatality. Proper testing of products containing borates must be performed in order to determine whether dosage and presentation are sufficient to kill insects.