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The hydrogen in ammonia is susceptible to replacement by a myriad substituents. Ammonia gas reacts with metallic sodium to give sodamide, NaNH 2. [38] With chlorine, monochloramine is formed. Pentavalent ammonia is known as λ 5-amine, nitrogen pentahydride decomposes spontaneously into trivalent ammonia (λ 3-amine) and hydrogen gas at normal ...
Fritz Haber, 1918. The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [2] [3] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
The reaction may otherwise involve the functional groups of the molecule, and is a versatile class of reactions that can occur in acidic or basic conditions or in the presence of a catalyst. This class of reactions is a vital part of life as it is essential to the formation of peptide bonds between amino acids and to the biosynthesis of fatty ...
The reaction occurring is: NH 4 F + HF → NH 4 HF 2. Ammonium fluoride sublimes when heated—a property common among ammonium salts. In the sublimation, the salt decomposes to ammonia and hydrogen fluoride; the two gases can still recombine, i.e. the reaction is reversible: [NH 4]F ⇌ NH 3 + HF
It is also miscible in common organic solvents, such as acetone, ethanol, and diethyl ether. Laboratory samples of triethylamine can be purified by distilling from calcium hydride. [11] In alkane solvents triethylamine is a Lewis base that forms adducts with a variety of Lewis acids, such as I 2 and phenols. Owing to its steric bulk, it forms ...
The Birch reduction is an organic reaction that is used to convert arenes to 1,4-cyclohexadienes.The reaction is named after the Australian chemist Arthur Birch and involves the organic reduction of aromatic rings in an amine solvent (traditionally liquid ammonia) with an alkali metal (traditionally sodium) and a proton source (traditionally an alcohol).
Ammonium bicarbonate decomposes above about 36 °C into ammonia, carbon dioxide, and water in an endothermic process and so causes a drop in the temperature of the water: NH 4 HCO 3 → NH 3 + H 2 O + CO 2. When treated with acids, ammonium salts are also produced: NH 4 HCO 3 + HCl → NH 4 Cl + CO 2 + H 2 O. Reaction with base produces ammonia.
The reaction between a ketone and ammonia results in an imine and byproduct water. This reaction is water sensitive and thus drying agents such as aluminum chloride or a Dean–Stark apparatus must be employed to remove water. The resulting imine will react and decompose back into the ketone and the ammonia when in the presence of water.