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The activation energy Q takes a different value depending on whether the high or low temperature limit is being considered: it changes from a high value Q H at low temperatures (in the glassy state) to a low value Q L at high temperatures (in the liquid state). Common logarithm of viscosity against temperature for B 2 O 3, showing two regimes
Dynamic viscosity is a material property which describes the resistance of a fluid to shearing flows. It corresponds roughly to the intuitive notion of a fluid's 'thickness'. For instance, honey has a much higher viscosity than water. Viscosity is measured using a viscometer. Measured values span several orders of magnitude.
The lower the VI, the more the viscosity is affected by changes in temperature. The higher the VI, the more stable the viscosity remains over some temperature range. The VI was originally measured on a scale from 0 to 100; however, advancements in lubrication science have led to the development of oils with much higher VIs.
Increasing temperature results in a decrease in viscosity because a larger temperature means particles have greater thermal energy and are more easily able to overcome the attractive forces binding them together. An everyday example of this viscosity decrease is cooking oil moving more fluidly in a hot frying pan than in a cold one.
Bond breaking modifies the properties of an amorphous material so that the higher the concentration of broken bonds termed configurons the lower the viscosity. Materials with a higher enthalpy of configuron formation compared with their enthalpy of motion have a higher Doremus fragility ratio, conversely melts with a relatively lower enthalpy ...
Viscosity; Rheopecty: The longer the fluid is subjected to a shear force, the higher the viscosity. Time-dependent shear thickening behavior. Thixotropy: The longer a fluid is subjected to a shear force, the lower its viscosity. It is a time-dependent shear thinning behavior.
For example, the viscosity of Venezuela's Orinoco extra-heavy crude oil lies in the range 1000–5000 cP (1–5 Pa·s), while Canadian extra-heavy crude has a viscosity in the range 5000–10,000 cP (5–10 Pa·s), about the same as molasses, and higher (up to 100,000 cP or 100 Pa·s for the most viscous commercially exploitable deposits). [2]
Shear thinning in a polymeric system: dependence of apparent viscosity on shear rate. η 0 is the zero shear rate viscosity and η ∞ is the infinite shear viscosity plateau. At both sufficiently high and very low shear rates, viscosity of a polymer system is independent of the shear rate.