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It constitutes around 38,000 Pg C [18] and includes dissolved carbon dioxide (CO 2), bicarbonate (HCO − 3), carbonate (CO 2− 3), and carbonic acid (H 2 C O 3). The equilibrium between carbonic acid and carbonate determines the pH of the seawater. Carbon dioxide dissolves easily in water and its solubility is inversely related to temperature.
The taste of soda water (and related taste sensations in other carbonated beverages) is an effect of the dissolved carbon dioxide rather than the bursting bubbles of the gas. Carbonic anhydrase 4 converts carbon dioxide to carbonic acid leading to a sour taste, and also the dissolved carbon dioxide induces a somatosensory response. [128]
In even a slight presence of water, carbonic acid dehydrates to carbon dioxide and water, which then catalyzes further decomposition. [6] For this reason, carbon dioxide can be considered the carbonic acid anhydride. The hydration equilibrium constant at 25 °C is [H 2 CO 3]/[CO 2] ≈ 1.7×10 −3 in pure water [12] and ≈ 1.2×10 −3 in ...
Carbon dioxide also dissolves directly from the atmosphere into bodies of water (ocean, lakes, etc.), as well as dissolving in precipitation as raindrops fall through the atmosphere. When dissolved in water, carbon dioxide reacts with water molecules and forms carbonic acid, which contributes to ocean acidity. It can then be absorbed by rocks ...
Dissolved inorganic carbon (DIC) is made up of bicarbonate (HCO 3 −), carbonate (CO 3 2−) and carbon dioxide (including both dissolved CO 2 and carbonic acid H 2 CO 3). DIC can be converted to particulate inorganic carbon (PIC) through precipitation of CaCO 3 (biologically or abiotically).
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.
Carbon dioxide forms carbonic acid when dissolved in water, so ocean acidification is a significant consequence of elevated carbon dioxide levels, and limits the rate at which it can be absorbed into the ocean (the solubility pump).
The exact value of the CCD depends on the solubility of calcium carbonate which is determined by temperature, pressure and the chemical composition of the water – in particular the amount of dissolved CO 2 in the water. Calcium carbonate is more soluble at lower temperatures and at higher pressures.