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As ammonium nitrate is a salt, both the cation, NH + 4, and the anion, NO − 3, may take part in chemical reactions. Solid ammonium nitrate decomposes on heating. At temperatures below around 300 °C, the decomposition mainly produces nitrous oxide and water: NH 4 NO 3 → N 2 O + 2 H 2 O. At higher temperatures, the following reaction ...
Ammonium nitrate decomposes in temperatures above 169 °C (336 °F). Pure AN is stable and will stop decomposing once the heat source is removed, but when catalysts are present, the reaction can become self-sustaining (known as self-sustaining decomposition, or SSD).
The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. Thermal decomposition is a chemical reaction where heat is a ...
Another example involving thermochemical equations is that when methane gas is combusted, heat is released, making the reaction exothermic. In the process, 890.4 kJ of heat is released per mole of reactants, so the heat is written as a product of the reaction.
The integral heat of dissolution is defined as a process of obtaining a certain amount of solution with a final concentration. The enthalpy change in this process, normalized by the mole number of solute, is evaluated as the molar integral heat of dissolution. Mathematically, the molar integral heat of dissolution is denoted as:
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On the evening of December 16, 1983, Mullis examined his purple-topped test tubes and saw for the first time that his idea actually worked. He told his lab assistant, Fred Faloona, that they had ...
Van 't Hoff plot for an endothermic reaction. For an endothermic reaction, heat is absorbed, making the net enthalpy change positive. Thus, according to the definition of the slope: =, When the reaction is endothermic, Δ r H > 0 (and the gas constant R > 0), so