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Hydrogen bonding plays an important role in determining the three-dimensional structures and the properties adopted by many proteins. Compared to the C−C, C−O, and C−N bonds that comprise most polymers, hydrogen bonds are far weaker, perhaps 5%. Thus, hydrogen bonds can be broken by chemical or mechanical means while retaining the basic ...
Hydrogen bonds formed among various monomers guarantee the construction of hydrogen-bonded organic frameworks with different assembly architectures. [15] [16] [17] The constitution of the hydrogen pairs is based on the structural and functional design of the HOFs, therefore different hydrogen bonding pairs should be selected following systematic requirements.
This process is of great interest because hydrogenation technology generates most of the trans fat in foods. A reaction where bonds are broken while hydrogen is added is called hydrogenolysis, a reaction that may occur to carbon-carbon and carbon-heteroatom (oxygen, nitrogen or halogen) bonds. Some hydrogenations of polar bonds are accompanied ...
The main engineering strategies currently in use are hydrogen-and halogen bonding and coordination bonding. [2] These may be understood with key concepts such as the supramolecular synthon and the secondary building unit. [3] An example of crystal engineering using hydrogen bonding reported by Wuest and coworkers in J. Am. Chem. Soc., 2007 ...
Sometimes grouped into the chemical mechanism of adhesion, hydrogen bonding can increase adhesive strength by the dispersive mechanism. [3] Hydrogen bonding occurs between molecules with a hydrogen atom attached to a small, electronegative atom such as fluorine , oxygen or nitrogen .
Starch gelatinization is a process of breaking down of intermolecular bonds of starch molecules in the presence of water and heat, allowing the hydrogen bonding sites (the hydroxyl hydrogen and oxygen) to engage more water. This irreversibly dissolves the starch granule in water. Water acts as a plasticizer.
Hydrogen bond forming organogelators include, amino acids/amides/urea moieties and carbohydrates whereas non-hydrogen bond forming organogelators (e.g. π-π stacking) include anthracene-, anthraquinone- and steroid-based molecules. [21] Solubility and/or solvent-molecule interactions play an important role in promoting organogelator self ...
Although hydrogen bonding is a relatively weak attraction compared to the covalent bonds within the water molecule itself, it is responsible for several of the water's physical properties. These properties include its relatively high melting and boiling point temperatures: more energy is required to break the hydrogen bonds between water molecules.