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Characteristic X-rays are emitted when outer-shell electrons fill a vacancy in the inner shell of an atom, releasing X-rays in a pattern that is "characteristic" to each element. Characteristic X-rays were discovered by Charles Glover Barkla in 1909, [ 1 ] who later won the Nobel Prize in Physics for his discovery in 1917.
An X-ray spectrograph consists of a high voltage power supply (50 kV or 100 kV), a broad band X-ray tube, usually with a tungsten anode and a beryllium window, a specimen holder, an analyzing crystal, a goniometer, and an X-ray detector device. These are arranged as shown in Fig. 1.
Tungsten occurs in many alloys, which have numerous applications, including incandescent light bulb filaments, X-ray tubes, electrodes in gas tungsten arc welding, superalloys, and radiation shielding. Tungsten's hardness and high density make it suitable for military applications in penetrating projectiles.
The Siegbahn notation is used in X-ray spectroscopy to name the spectral lines that are characteristic to elements. It was introduced by Manne Siegbahn.. The characteristic lines in X-ray emission spectra correspond to atomic electronic transitions where an electron jumps down to a vacancy in one of the inner shells of an atom.
Tungsten is a good source for producing this kind of radiation due to its high atomic number and high melting point. The high-energy electrons formed in the cathode side of an X-ray tube can interact with the electrons of a tungsten target on the anode side and produce ionized radiation or white radiation.
Moseley's law is an empirical law concerning the characteristic X-rays emitted by atoms. The law had been discovered and published by the English physicist Henry Moseley in 1913–1914. [ 1 ] [ 2 ] Until Moseley's work, "atomic number" was merely an element's place in the periodic table and was not known to be associated with any measurable ...
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Spectrum of the X-rays emitted by an X-ray tube with a rhodium target, operated at 60 kV. The smooth, continuous curve is due to bremsstrahlung, and the spikes are characteristic K lines for rhodium atoms. Note that the emission starts around wavelength of 20pm corresponding to E=hc/λ.