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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
It can be made by oxidising nickel nitrate in a cold alkaline solution with bromine. A mixed oxidation state hydroxide Ni 3 O 2 (OH) 4 is made if oxidation happens in a hot alkaline solution. A Ni 4+ hydroxide: nickel peroxide hydrate NiO 2 · H 2 O, can be made by oxidising with alkaline peroxide. It is black, and unstable and oxidises water.
Nickel(II) perchlorate is a collection of inorganic compounds with the chemical formula of Ni(ClO 4) 2 (H 2 O) x.Its colors of these solids vary with the degree of hydration. For example, the hydrate forms cyan crystals, the pentahydrate forms green crystals, but the hexahydrate (Ni(ClO 4) 2 ·6H 2 O) forms blue crystals.
Nickel(II) thiocyanate can be prepared via salt metathesis using the reaction of methanolic solutions of KSCN and nickel(II) perchlorate hexahydrate, filtering off the precipitated KClO 4 to yield a solution of Ni(SCN) 2. On removal of the methanol, a pure microcrystalline powder of Ni(SCN) 2 can be obtained.
Nickel terephthalate can be made by a double decomposition of sodium terephthalate and nickel nitrate. Nickel terephthalate precipitates. Its solubility is 0.38 g/100g water at 25 °C. In ammonium hydroxide a violet solution forms. Boiling acetic acid converts the nickel to nickel acetate.
Nickel nitrate commonly crystallises with six water molecules, [1] but can also be anhydrous, or with two, four or nine waters. [11] triphenylphosphine oxide nickel nitrate [(C 6 H 6) 3 PO] 2 Ni(NO 3) 2 is non ionic, with nitrato as a ligand. It can be made from nickel perchlorate. It is yellow and melts at 266 °C. [12]
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Europium(III) nitrate can be obtained by reacting europium(III) oxide and nitric acid and crystallizing. The crystal is dried with 45~55% sulfuric acid to obtain hexahydrate. [58] Its anhydrous form can be obtained by the reaction of europium oxide and dinitrogen tetroxide, while heating the hydrate can only obtain the basic salt EuONO 3. [59]