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The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), [ 1 ] which are commodity chemicals required by industry.
Another earlier process to produce chlorine was to heat brine with acid and manganese dioxide. 2 NaCl + 2H 2 SO 4 + MnO 2 → Na 2 SO 4 + MnSO 4 + 2 H 2 O + Cl 2. Using this process, chemist Carl Wilhelm Scheele was the first to isolate chlorine in a laboratory. The manganese can be recovered by the Weldon process. [11]
A mixed oxidant solution (MOS) is a type of disinfectant that has many uses including disinfecting, sterilizing, and eliminating pathogenic microorganisms in water. [1] An MOS may have advantages such as a higher disinfecting power, stable residual chlorine in water, elimination of biofilm, and safety. [2]
The chlor-alkali industry is a major consumer of the world's energy budget. This process converts concentrated sodium chloride solutions into chlorine and sodium hydroxide, which are used to make many other materials and chemicals. The process involves two parallel reactions: 2 Cl − → Cl 2 + 2 e − 2 H 2 O + 2 e − → H 2 + 2 OH −
The Castner–Kellner process is a method of electrolysis on an aqueous alkali chloride solution (usually sodium chloride solution) to produce the corresponding alkali hydroxide, [1] invented by American Hamilton Castner and Austrian Carl Kellner in the 1890s.
The process of electrochlorination is a simple application based on the chloralkali process (in an unpartitioned cell). It is the electrolysis of saltwater to produce a chlorinated solution. The first step is removing any solids from the saltwater. Next, the saltwater streams through an electrolyzer cell's channel of decreasing thickness.
English: Membrane chloralkali process. At the anode (A), chloride (Cl-) is oxidized to chlorine.The ion-selective membrane (B) allows the counterion Na+ to freely flow across, but prevents anions such as hydroxide (OH-) and chloride from diffusing across.
After the war, the Olins acquired the Mathieson Chemical Corporation—also founded in 1892. [8] [9] [10] Long before its association with Olin, Mathieson Alkali Works began business in Saltville, Virginia, and a year later acquired its neighbor, the Holston Salt and Plaster Corp. Saltville became a quintessential company town, where they produced chlorine and caustic soda, and in the process ...