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The main polycarbonate material is produced by the reaction of bisphenol A (BPA) and phosgene COCl 2. The overall reaction can be written as follows: The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A. [6] (HOC 6 H 4) 2 CMe 2 + 2 NaOH → Na 2 (OC 6 ...
Photodissociation involves the formation of an excited terephthalic acid unit which undergoes Norrish reactions. The type I reaction dominates, which cause chain scission at the carbonyl unit to give a range of products. [1] [38] Type II Norrish reactions are less common but give rise to acetaldehyde by way of vinyl alcohol esters. [36]
Poly(trimethylene carbonate) (PTMC) is an aliphatic polycarbonate synthesized from the 6-membered cyclic carbonate, trimethylene carbonate (1,3-propylene carbonate or 1,3-Dioxan-2-one). Trimethylene carbonate (TMC) is a colorless crystalline solid with melting point ranging between 45°C and 48 °C and boiling point at 255°C (at 760 mmHg).
Because the yields are low this procedure is not used in commercial production. However, photo-Fries rearrangement may occur naturally, for example when a plastic object made of aromatic polycarbonate, polyester or polyurethane, is exposed to the sun (aliphatic carbonyls undergo Norrish reactions, which are somewhat
For radical polymerization, termination involves a reaction of two growing polymer chains to eliminate the unpaired electrons of both chains. There are two possibilities. [8] 1. Recombination is the reaction of the unpaired electrons of two chains to form a covalent bond between them. The product is a single polymer molecule with the combined ...
Polycarbonate polyols are more expensive than other polyols and are thus used in more demanding applications. [31] [32] They have been used to make an isophorone diisocyanate based prepolymer which is then used in glass coatings. [33] They may be used in reactive hotmelt adhesives. [34] All polyols may be used to produce polyurethane prepolymers.
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The unique O=C bond is short (1.173 Å in the depicted example), while the C-O bonds are more ether-like (the bond distances of 1.326 Å for the example depicted). [1] Carbonate esters can be divided into three structural classes: acyclic, cyclic, and polymeric. The first and general case is the acyclic carbonate group.
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