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Trimethyl phosphate is a mild methylating agent, useful for dimethylation of anilines and related heterocyclic compounds. [2] The method is complementary to the traditional Eschweiler-Clarke reaction in cases where formaldehyde engages in side reactions.
It was founded by East Pakistan Industrial Development Corporation (EPIDC) before the independence of Bangladesh and went into commercial production in 1974. [4] Among the units TSP-II was commissioned earlier in September 1974 and TSP-I unit went into commercial production in April 1977.
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As a ligand, trimethyl phosphite has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex Ni(P(OMe) 3) 4 (m.p. 108 °C). [4] The tridentate ligand called the Kläui ligand is derived from trimethyl phosphite. The formation of this ligand illustrates ...
Trimethylphosphine is a highly basic ligand that forms complexes with most metals. As a ligand, trimethylphosphine's Tolman cone angle is 118°. [7] This angle is an indication of the amount of steric protection that this ligand provides to the metal that to which it is bound.
In 1982, it set up the first tiles factory in Bangladesh. [10] It is subsidized by Bangladesh government. [11] The Training Institute for Chemical Industries (TICI) is a sister concern of BCIC and is run by BCIC too. [12] Chittagong Urea Fertilizer School and College falls under this corporation, [13] as does Urea Sar Karkhana School & College ...
Bangladesh Insulator and Sanitaryware Factory Limited; Bangladesh Jute Mills Corporation; Bangladesh Machine Tools Factory; Bangladesh Municipal Development Fund [1] Bangladesh Ordnance Factories; Bangladesh Overseas Employment and Services Limited; Bangladesh Parjatan Corporation; Bangladesh Petroleum Exploration and Production Company Limited
Phosphites are oxidized to phosphate esters: P(OR) 3 + [O] → OP(OR) 3. This reaction underpins the commercial use of some phosphite esters as stabilizers in polymers. [6] Alkyl phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates.