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Several routes exist for the production of cyclohexenone. For the laboratory scale, it can be produced from resorcinol via 1,3-cyclohexanedione. [6] Cyclohexenone is obtained by Birch reduction of anisole followed by acid hydrolysis. It can be obtained from cyclohexanone by α-bromination followed by treatment with base.
The simplest case refers to the formation of a strictly linear polymer by the reaction (usually by condensation) of two monomers in equimolar quantities. An example is the synthesis of nylon-6,6 whose formula is [−NH−(CH 2) 6 −NH−CO−(CH 2) 4 −CO−] n from one mole of hexamethylenediamine, H 2 N(CH 2) 6 NH 2, and one mole of adipic acid, HOOC−(CH 2) 4 −COOH.
1,2-Cyclohexanedione is an organic compound with the formula (CH 2) 4 (CO) 2. It is one of three isomeric cyclohexanediones. It is a colorless compound that is soluble in a variety of organic solvents. It can be prepared by oxidation of cyclohexanone by selenium dioxide. [1] The enol is about 1 kcal/mol more stable than the diketo form. [2]
The yield strength or yield stress is a material property and is the stress corresponding to the yield point at which the material begins to deform plastically. The yield strength is often used to determine the maximum allowable load in a mechanical component, since it represents the upper limit to forces that can be applied without producing ...
Adipic acid or hexanedioic acid is the organic compound with the formula (CH 2) 4 (COOH) 2.From an industrial perspective, it is the most important dicarboxylic acid: about 2.5 billion kilograms of this white crystalline powder are produced annually, mainly as a precursor for the production of nylon.
A solution with 1 g of solute dissolved in a final volume of 100 mL of solution would be labeled as "1%" or "1% m/v" (mass/volume). This is incorrect because the unit "%" can only be used for dimensionless quantities.
Approximately 95% of hydroxylamine is used in the synthesis of cyclohexanone oxime, a precursor to Nylon 6. [10] The treatment of this oxime with acid induces the Beckmann rearrangement to give caprolactam (3). [21] The latter can then undergo a ring-opening polymerization to yield Nylon 6. [22]
In terms of functional group selectivity, alane differs from other hydride reagents. For example, in the following cyclohexanone reduction, lithium aluminium hydride gives a trans:cis ratio of 1.9 : 1, whereas aluminium hydride gives a trans:cis ratio of 7.3 : 1. [33] Stereoselective reduction of a substituted cyclohexanone using aluminium hydride