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Standard electrode potential. In electrochemistry, standard electrode potential , or , is a measure of the reducing power of any element or compound. The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left ...
Electrode potential. In electrochemistry, electrode potential is the voltage of a galvanic cell built from a standard reference electrode and another electrode to be characterized. [1] By convention, the reference electrode is the standard hydrogen electrode (SHE). It is defined to have a potential of zero volts.
Nernst equation. In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often ...
Standard electrode potential (data page) The data below tabulates standard electrode potentials (E °), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent ...
Galvanic cell with no cation flow. A galvanic cell or voltaic cell, named after the scientists Luigi Galvani and Alessandro Volta, respectively, is an electrochemical cell in which an electric current is generated from spontaneous oxidation–reduction reactions. A common apparatus generally consists of two different metals, each immersed in ...
Standard hydrogen electrode. In electrochemistry, the standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction potentials. Its absolute electrode potential is estimated to be 4.44 ± 0.02 V[ 1 ] at 25 °C, but to form a basis for comparison with all other ...
The lower graph shows the logarithmic plot for different values of α (Tafel plot). The Butler–Volmer equation is: or in a more compact form: where: : electrode current density, A/m 2 (defined as j = I/S) : exchange current density, A/m 2. : electrode potential, V. : equilibrium potential, V.
Electrochemistry. English chemist John Daniell (left) and physicist Michael Faraday (right), both credited as founders of electrochemistry. Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an ...