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If the concentration of a reactant remains constant (because it is a catalyst, or because it is in great excess with respect to the other reactants), its concentration can be included in the rate constant, leading to a pseudo–first-order (or occasionally pseudo–second-order) rate equation. For a typical second-order reaction with rate ...
For a random sample as above, with cumulative distribution (), the order statistics for that sample have cumulative distributions as follows [2] (where r specifies which order statistic): () = = [()] [()] The proof of this formula is pure combinatorics: for the th order statistic to be , the number of samples that are > has to be between and .
First-order approximation is the term scientists use for a slightly better answer. [3] Some simplifying assumptions are made, and when a number is needed, an answer with only one significant figure is often given ("the town has 4 × 10 3, or four thousand, residents"). In the case of a first-order approximation, at least one number given is exact.
For example, the second-order equation y′′ = −y can be rewritten as two first-order equations: y′ = z and z′ = −y. In this section, we describe numerical methods for IVPs, and remark that boundary value problems (BVPs) require a different set of tools. In a BVP, one defines values, or components of the solution y at more than one ...
Order Equation Application Reference Abel's differential equation of the first kind: 1 = + + + Class of differential equation which may be solved implicitly [1] Abel's differential equation of the second kind: 1
In fact, however, the observed reaction rate is second-order in NO 2 and zero-order in CO, [5] with rate equation r = k[NO 2] 2. This suggests that the rate is determined by a step in which two NO 2 molecules react, with the CO molecule entering at another, faster, step. A possible mechanism in two elementary steps that explains the rate ...
Runge–Kutta–Nyström methods are specialized Runge–Kutta methods that are optimized for second-order differential equations. [22] [23] A general Runge–Kutta–Nyström method for a second-order ODE system ¨ = (,, …,) with order is with the form
For instance, ideally the solution of a differential equation discretized via a regular grid will converge to the solution of the continuous equation as the grid spacing goes to zero, and if so the asymptotic rate and order of that convergence are important properties of the gridding method.