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In general, hydrogen sulfide acts as a reducing agent, as indicated by its ability to reduce sulfur dioxide in the Claus process. Hydrogen sulfide burns in oxygen with a blue flame to form sulfur dioxide (SO 2) and water: 2 H 2 S + 3 O 2 → 2 SO 2 + 2 H 2 O
Sulfur dioxide is a mild but useful reducing agent. It is oxidized by halogens to give the sulfuryl halides, such as sulfuryl chloride: SO 2 + Cl 2 → SO 2 Cl 2. Sulfur dioxide is the oxidising agent in the Claus process, which is conducted on a large scale in oil refineries. Here, sulfur dioxide is reduced by hydrogen sulfide to give ...
This volcano released huge quantities of stratospheric sulfur aerosols and contributed greatly to understanding of the subject. Various forms of sulfur were proposed as the injected substance, as this is in part how volcanic eruptions cool the planet. [6] Precursor gases such as sulfur dioxide and hydrogen sulfide have been considered ...
The principal components of volcanic gases are water vapor (H 2 O), carbon dioxide (CO 2), sulfur either as sulfur dioxide (SO 2) (high-temperature volcanic gases) or hydrogen sulfide (H 2 S) (low-temperature volcanic gases), nitrogen, argon, helium, neon, methane, carbon monoxide and hydrogen.
Reduced sulfur compounds, such as hydrogen sulfide, elemental sulfur, sulfite, thiosulfate, and various polythionates (e.g., tetrathionate), are oxidized by chemotrophic, phototrophic, and mixotrophic bacteria for energy. [1] Some chemosynthetic archaea use hydrogen sulfide as an energy source for carbon fixation, producing sugars.
Some metal sulfides, when exposed to a strong mineral acid, including gastric acids, will release toxic hydrogen sulfide. Organic sulfides are highly flammable. When a sulfide burns it produces sulfur dioxide (SO 2) gas. Hydrogen sulfide, some of its salts, and almost all organic sulfides have a strong and putrid stench; rotting biomass ...
[1] [2] Anaerobic sulfur oxidizers include photolithoautotrophs that obtain their energy from sunlight, hydrogen from sulfide, and carbon from carbon dioxide (CO 2). [3] Most of the sulfur oxidizers are autotrophs that can use reduced sulfur species as electron donors for CO 2 fixation.
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.