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The pressure swing adsorption (PSA) process is based on the phenomenon that under high pressure, gases tend to be trapped onto solid surfaces, i.e. to be "adsorbed". The higher the pressure, the more gas is adsorbed. When the pressure is dropped, the gas is released, or desorbed.
gas molecules only interact with adjacent layers; and; the Langmuir theory can be applied to each layer. the enthalpy of adsorption for the first layer is constant and greater than the second (and higher). the enthalpy of adsorption for the second (and higher) layers is the same as the enthalpy of liquefaction. The resulting BET equation is
Brunauer, Emmett and Teller's model of multilayer adsorption is a random distribution of molecules on the material surface. Adsorption is the adhesion [1] of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. [2] This process creates a film of the adsorbate on the surface of the adsorbent.
The adsorption sites (heavy dots) are equivalent and can have unit occupancy. Also, the adsorbates are immobile on the surface. The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes.
Vacuum swing adsorption (VSA) uses the same principle as PSA but swings between vacuum pressures and atmospheric pressure. [2] PSA and VSA techniques may be combined and are called "vacuum pressure swing adsorption" (VPSA) in this case.
Thermogravimetric analysis or thermal gravimetric analysis (TGA) is a method of thermal analysis in which the mass of a sample is measured over time as the temperature changes. . This measurement provides information about physical phenomena, such as phase transitions, absorption, adsorption and desorption; as well as chemical phenomena including chemisorptions, thermal decomposition, and ...
Pressure swing adsorption – Selective adsorption of gas on a medium which is reversible and proportional to pressure. Gas is loaded onto the medium during the high pressure phase and is released during the low pressure phase. Membrane gas separation – Gas is forced through a semi-permeable membrane by a pressure difference. Some of the ...
The Hertz–Knudsen equation describes the non-dissociative adsorption of a gas molecule on a surface by expressing the variation of the number of molecules impacting on the surfaces per unit of time as a function of the pressure of the gas and other parameters which characterise both the gas phase molecule and the surface: [1] [2]