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According to the correspondence principle, in certain limits the quantum equations of states must approach Hamilton's equations of motion.The latter state the following relation between the generalized coordinate q (e.g. position) and the generalized momentum p: {˙ = = {,}; ˙ = = {,}.
These commutation relations are relevant for measurement and uncertainty, as discussed further below. In molecules the total angular momentum F is the sum of the rovibronic (orbital) angular momentum N, the electron spin angular momentum S, and the nuclear spin angular momentum I.
Ladder operator. In linear algebra (and its application to quantum mechanics), a raising or lowering operator (collectively known as ladder operators) is an operator that increases or decreases the eigenvalue of another operator. In quantum mechanics, the raising operator is sometimes called the creation operator, and the lowering operator the ...
Creation and annihilation operators. Creation operators and annihilation operators are mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. [1] An annihilation operator (usually denoted ) lowers the number of particles in a given state by one.
In mathematics, the Baker–Campbell–Hausdorff formula gives the value of that solves the equation for possibly noncommutative X and Y in the Lie algebra of a Lie group. There are various ways of writing the formula, but all ultimately yield an expression for in Lie algebraic terms, that is, as a formal series (not necessarily convergent) in ...
The angular momentum of m is proportional to the perpendicular component v ⊥ of the velocity, or equivalently, to the perpendicular distance r ⊥ from the origin. Angular momentum is a vector quantity (more precisely, a pseudovector) that represents the product of a body's rotational inertia and rotational velocity (in radians/sec) about a ...
Stone–von Neumann theorem. In mathematics and in theoretical physics, the Stone–von Neumann theorem refers to any one of a number of different formulations of the uniqueness of the canonical commutation relations between position and momentum operators. It is named after Marshall Stone and John von Neumann. [1][2][3][4]
In physics, the Clebsch–Gordan (CG) coefficients are numbers that arise in angular momentum coupling in quantum mechanics. They appear as the expansion coefficients of total angular momentum eigenstates in an uncoupled tensor product basis. In more mathematical terms, the CG coefficients are used in representation theory, particularly of ...