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Left: individual linear polymer chains Right: Polymer chains which have been cross linked to give a rigid 3D thermoset polymer. In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (). [1]
Recycling codes on products. Recycling codes are used to identify the materials out of which the item is made, to facilitate easier recycling process.The presence on an item of a recycling code, a chasing arrows logo, or a resin code, is not an automatic indicator that a material is recyclable; it is an explanation of what the item is made of.
Conventional PU foams are cross-linked materials or thermosets. PU foams can either be mechanically recycled (where PU foams are grinded and used as fillers), or chemically recycled (where PU foams are downcycled into polyols or other monomeric components via chemical degradation). [16] [17] However, most PU foams end up on landfills.
These are made by the reaction of phenols, formaldehyde and primary amines which at elevated temperatures (400 °F (200 °C)) undergo ring–opening polymerisation forming polybenzoxazine thermoset networks; when hybridised with epoxy and phenolic resins the resulting ternary systems have glass transition temperatures in excess of 490 °F (250 °C).
The main carboxylating enzyme in C 3 photosynthesis is called RuBisCO, which catalyses two distinct reactions using either CO 2 (carboxylation) or oxygen (oxygenation) as a substrate. RuBisCO oxygenation gives rise to phosphoglycolate, which is toxic and requires the expenditure of energy to recycle through photorespiration.
Thermosets, or thermosetting polymers, can melt and take shape only once: after they have solidified, they stay solid and retain their shape permanently. [16] If reheated, thermosets decompose rather than melt. Examples of thermosets include epoxy resin, polyimide, and Bakelite. The vulcanization of rubber is an example of this process.
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
C 2 photosynthesis (also called glycine shuttle and photorespiratory CO 2 pump) is a CCM that works by making use of – as opposed to avoiding – photorespiration. It performs carbon refixation by delaying the breakdown of photorespired glycine, so that the molecule is shuttled from the mesophyll into the bundle sheath .