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This reagent is generated by treating 9-BBN with α-pinene. [2] This sterically crowded chiral trialkylborane can stereoselectively reduce aldehydes in what is known as the Midland Alpine borane reduction, or simply the Midland reduction. [3] C 8 H 12 B-pinanyl + RCDO → C 8 H 12 BOCHDR + (+)-d-pinene. Hydrolysis of the resulting borinic ester ...
In the same year, M. M. Midland discovered B-3-alpha-pinanyl-9-BBN as the reducing agent, which could be easily available by reacting (+)-alpha-pinene with 9-BBN. The new reducing agent was later commercialized by Aldrich Co. under the name Alpine Borane and the asymmetric reduction of carbonyl groups with either enantiomer of Alpine-Borane is ...
9-Borabicyclo[3.3.1]nonane or 9-BBN is an organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily cleaves in the presence of reducible substrates. [1] 9-BBN is also known by its nickname 'banana borane'. [2]
Penn State is a win away from the national title game. The No. 6 Nittany Lions jumped out to a 14-0 lead and held on for a 31-14 win over No. 3 Boise State in the Fiesta Bowl. PSU advances to the ...
These dogs are truly deserving of a little fun in their lives. As the rescue themselves noted, many of the dogs are in hospice care with cancer, renal failure, or other serious health issues. So ...
Ariana Grande, the pop music and "Wicked" star, is speaking out about comments surrounding her body, calling the comments "horrible."
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Every generation views their health and wellness differently. For older Americans, mental health diagnoses are becoming more prevalent. Between 2019 and 2023, the 65+ age group collectively ...