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In organic chemistry, the Myers allene synthesis is a chemical reaction that converts a propargyl alcohol into an allene by way of an arenesulfonyl hydrazine as a key intermediate. [1] This name reaction is one of two discovered by Andrew Myers that are named after him; both this reaction and the Myers deoxygenation reaction involve the same ...
In organic chemistry, the Myers deoxygenation reaction is an organic redox reaction that reduces an alcohol into an alkyl position by way of an arenesulfonyl hydrazine as a key intermediate. This name reaction is one of four discovered by Andrew Myers that are named after him; this reaction and the Myers allene synthesis reaction involve the ...
In the Arndt–Eistert reaction, an α-diazoketone is induced to release N 2, resulting in a highly reactive sextet carbon center adjacent to the carbonyl. Such species convert by a Wolff rearrangement to give an ester in the presence of alcohols. When applied to cyclic α-diazoketones, ring contraction occurs.
The program came about as the result of the Inflation Reduction Act, which included $15 million in funding to study the creation of a website allowing Americans to directly file their taxes to the ...
Japanese pitcher Roki Sasaki remains one of the biggest free agents available. Here are the latest rumors surrounding the international star.
A former Allianz fund manager was spared prison time on Friday over his role in a meltdown of private investment funds sparked by the COVID-19 pandemic that caused an estimated $7 billion of ...
In stereochemistry, a chiral auxiliary is a stereogenic group or unit that is temporarily incorporated into an organic compound in order to control the stereochemical outcome of the synthesis. [1] [2] The chirality present in the auxiliary can bias the stereoselectivity of one or more subsequent reactions. The auxiliary can then be typically ...
The semifinals of the 12-team College Football Playoff are set, and no conference champions remain.. All four of the teams still alive in the playoff hosted games in the first round of the playoff ...