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Melting point: −111.9 °C (− ... Propylene oxide is an acutely toxic and carcinogenic organic compound ... This technology was commercialized by Sumitomo Chemical.
Polypropylene glycol or polypropylene oxide is the polymer (or macromolecule) of propylene glycol. [1] Chemically it is a polyether , and, more generally speaking, it's a polyalkylene glycol (PAG) H S Code 3907.2000.
Propylene is also used to produce isopropyl alcohol (propan-2-ol), acrylonitrile, propylene oxide, and epichlorohydrin. [18] The industrial production of acrylic acid involves the catalytic partial oxidation of propylene. [19] Propylene is an intermediate in the oxidation to acrylic acid.
A typical well-known method of preparation is the reaction of potassium hydroxide with 3-chloropropyl acetate at 150 °C: [2]. Yield of oxetane made this way is c. 40%, as the synthesis can lead to a variety of by-products including water, potassium chloride, and potassium acetate.
Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers.This colourless gas is the epoxide of hexafluoropropylene, which is a fluorinated analog of propylene oxide, HFPO is produced by Chemours and 3M and as a precursor to the lubricant Krytox and related materials.
Poly(p-phenylene oxide) (PPO), poly(p-phenylene ether) (PPE), poly(oxy-2,6-dimethyl-1,4-phenylene), often referred to simply as polyphenylene oxide, is a high-temperature thermoplastic with the general formula (C 8 H 8 O) n. It is rarely used in its pure form due to difficulties in processing.
The nominal chemical formula of P123 is HO(CH 2 CH 2 O) 20 (CH 2 CH(CH 3)O) 70 (CH 2 CH 2 O) 20 H, which corresponds to a molecular weight of around 5800 g/mol. Triblock copolymers based on PEO-PPO-PEO chains are known generically as poloxamer.
Industrially, tert-butyl hydroperoxide is used to prepare propylene oxide. In the Halcon process, molybdenum-based catalysts are used for this reaction: (CH 3) 3 COOH + CH 2 =CHCH 3 → (CH 3) 3 COH + CH 2 OCHCH 3. The byproduct t-butanol can be dehydrated to isobutene and converted to MTBE.