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Trend-wise, as one moves from left to right across a period in the modern periodic table, the electronegativity increases as the nuclear charge increases and the atomic size decreases. However, if one moves down in a group , the electronegativity decreases as atomic size increases due to the addition of a valence shell , thereby decreasing the ...
The halogens (/ ˈ h æ l ə dʒ ə n, ˈ h eɪ-,-l oʊ-,-ˌ dʒ ɛ n / [1] [2] [3]) are a group in the periodic table consisting of six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and tennessine (Ts), though some authors [4] would exclude tennessine as its chemistry is unknown and is theoretically expected to ...
It is important to note that the list given above is qualitative and describes trends. The ability of a group to leave is contextual. For example, in S N Ar reactions, the rate is generally increased when the leaving group is fluoride relative to the other halogens. This effect is due to the fact that the highest energy transition state for ...
Although all halogens can theoretically participate in halogen bonds, the σ-hole shrinks if the electron cloud in question polarizes poorly or the halogen is so electronegative as to polarize the associated σ-bond. [3] [9] Consequently halogen-bond propensity follows the trend [10] [Note 1] F < Cl < Br < I.
Following the usual trend, bromine is less reactive and iodine least of all. Of the many reactions possible, illustrative is the formation of gold(III) chloride by the chlorination of gold . The chlorination of metals is usually not very important industrially since the chlorides are more easily made from the oxides and hydrogen chloride .
The relative rates at which different halogens react vary considerably: [citation needed] fluorine (108) > chlorine (1) > bromine (7 × 10 −11) > iodine (2 × 10 −22).. Radical fluorination with the pure element is difficult to control and highly exothermic; care must be taken to prevent an explosion or a runaway reaction.
It has a characteristic halogen-like pungent and biting odor detectable at 20 ppb. [43] Fluorine condenses into a bright yellow liquid at −188 °C (−306.4 °F), a transition temperature similar to those of oxygen and nitrogen. [44] Fluorine has two solid forms, α- and β-fluorine.
For example, halogens get darker with increasing atomic weight – fluorine is nearly colorless, chlorine is yellow-green, bromine is red-brown, and iodine is dark gray/violet. Astatine is sometimes described as probably being a black solid (assuming it follows this trend), or as having a metallic appearance (if it is a metalloid or a metal).