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  2. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    [1]: 416 The geometry of the central atoms and their non-bonding electron pairs in turn determine the geometry of the larger whole molecule. The number of electron pairs in the valence shell of a central atom is determined after drawing the Lewis structure of the molecule, and expanding it to show all bonding groups and lone pairs of electrons.

  3. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecular geometry. Geometry of the water molecule with values for O-H bond length and for H-O-H bond angle between two bonds. Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other ...

  4. Linear molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Linear_molecular_geometry

    The linear molecular geometry describes the geometry around a central atom bonded to two other atoms (or ligands) placed at a bond angle of 180°. Linear organic molecules, such as acetylene (HC≡CH), are often described by invoking sp orbital hybridization for their carbon centers. According to the VSEPR model (Valence Shell Electron Pair ...

  5. Electron pair - Wikipedia

    en.wikipedia.org/wiki/Electron_pair

    In chemistry, an electron pair or Lewis pair consists of two electrons that occupy the same molecular orbital but have opposite spins. Gilbert N. Lewis introduced the concepts of both the electron pair and the covalent bond in a landmark paper he published in 1916. [1][2] MO diagrams depicting covalent (left) and polar covalent (right) bonding ...

  6. Polyhedral skeletal electron pair theory - Wikipedia

    en.wikipedia.org/wiki/Polyhedral_skeletal...

    If the electron count is close to 5 electrons per vertex, the structure often changes to one governed by the 5n rules, which are based on 3-connected polyhedra. As the electron count increases further, the structures of clusters with 5n electron counts become unstable, so the 6 n rules can be implemented.

  7. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    [11] [12] This electron distance maximization happens to achieve the most stable electron distribution. [11] [12] The result of VSEPR theory is being able to predict bond angles with accuracy. According to VSEPR theory, the geometry of a molecule can be predicted by counting how many electron pairs and atoms are connected to a central atom.

  8. Trigonal bipyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_bipyramidal...

    Trigonal bipyramidal molecular geometry. In chemistry, a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular bipyramid. [1] This is one geometry for which the bond angles surrounding the central atom are not identical (see also pentagonal bipyramid), because there is ...

  9. T-shaped molecular geometry - Wikipedia

    en.wikipedia.org/wiki/T-shaped_molecular_geometry

    The T-shaped geometry is related to the trigonal bipyramidal molecular geometry for AX 5 molecules with three equatorial and two axial ligands. In an AX 3 E 2 molecule, the two lone pairs occupy two equatorial positions, and the three ligand atoms occupy the two axial positions as well as one equatorial position. The three atoms bond at 90 ...