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A graft polymer molecule is a branched polymer molecule in which one or more of the side chains are different, structurally or configurationally, from the main chain. A star-shaped polymer molecule is a branched polymer molecule in which a single branch point gives rise to multiple linear chains or arms.
Branched polymers are formed as monomer adds to the new radical site which is located along the polymer backbone. The properties of low-density polyethylene are critically determined by the amount of chain transfer to polymer that takes place. Chain transfer from polypropylene to backbone of another polypropylene. Transfer to solvent.
The easiest way to visualize the mechanism of a step-growth polymerization is a group of people reaching out to hold their hands to form a human chain—each person has two hands (= reactive sites). There also is the possibility to have more than two reactive sites on a monomer: In this case branched polymers production take place.
Branch point in a polymer. Polymer architecture in polymer science relates to the way branching leads to a deviation from a strictly linear polymer chain. [1] Branching may occur randomly or reactions may be designed so that specific architectures are targeted. [1] It is an important microstructural feature.
At this second resting state, the ethylene molecule can insert to grow the polymer or dissociate inducing further chain walking. If many branches can form, a hyperbranched topology results. Therefore, ethene only homopolymerization can provide branched polymer whereas the same mechanism leads to chain straightening in α-olefin polymerization. [8]
Graft copolymers are a branched copolymer where the components of the side chain are structurally different than that of the main chain. Graft copolymers containing a larger quantity of side chains are capable of wormlike conformation, compact molecular dimension, and notable chain end effects due to their confined and tight fit structures. [1]
Crystal structure of a first-generation polyphenylene dendrimer reported by Müllen et al [5] A first-generation "cyanostar" dendrimer and its STM image [6]. The first dendrimers were made by divergent synthesis approaches by Fritz Vögtle in 1978, [7] R.G. Denkewalter at Allied Corporation in 1981, [8] [9] Donald Tomalia at Dow Chemical in 1983 [10] and in 1985, [11] [12] and by George R ...
Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units ...