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Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydrates. In the form of γ- anhydrite (the anhydrous form), it is used as a desiccant . One particular hydrate is better known as plaster of Paris , and another occurs naturally as the mineral gypsum .
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Due to the large size of the calcium ion (Ca 2+), high coordination numbers are common, up to 24 in some intermetallic compounds such as CaZn 13. [21] Calcium is readily complexed by oxygen chelates such as EDTA and polyphosphates , which are useful in analytic chemistry and removing calcium ions from hard water .
The sulfate ion can act as a ligand attaching either by one oxygen (monodentate) or by two oxygens as either a chelate or a bridge. [7] An example is the complex Co 2 (SO 4)] + Br − [7] or the neutral metal complex PtSO 4 (PPh 3) 2] where the sulfate ion is acting as a bidentate ligand. The metal–oxygen bonds in sulfate complexes can have ...
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion).
Calcium sulfite, or calcium sulphite, is a chemical compound, the calcium salt of sulfite with the formula CaSO 3 ·x(H 2 O). Two crystalline forms are known, the hemihydrate and the tetrahydrate, respectively CaSO 3 ·½(H 2 O) and CaSO 3 ·4(H 2 O). [2] All forms are white solids. It is most notable as the product of flue-gas desulfurization.
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Calcium bisulfite (calcium bisulphite or calcium hydrogen sulfite) is an inorganic compound which is the salt of a calcium cation and a bisulfite anion. It may be prepared by treating lime with an excess of sulfur dioxide and water.