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  2. Unpaired electron - Wikipedia

    en.wikipedia.org/wiki/Unpaired_electron

    The ions with the largest number of unpaired electrons are Gd 3+ and Cm 3+ with seven unpaired electrons. An unpaired electron has a magnetic dipole moment, while an electron pair has no dipole moment because the two electrons have opposite spins so their magnetic dipole fields are in opposite directions and cancel. Thus an atom with unpaired ...

  3. Ligand field theory - Wikipedia

    en.wikipedia.org/wiki/Ligand_field_theory

    In complexes of metals with these d-electron configurations, the non-bonding and anti-bonding molecular orbitals can be filled in two ways: one in which as many electrons as possible are put in the non-bonding orbitals before filling the anti-bonding orbitals, and one in which as many unpaired electrons as possible are put in. The former case ...

  4. Hund's cases - Wikipedia

    en.wikipedia.org/wiki/Hund's_cases

    Another example is the 3 Σ ground state of dioxygen, which has two unpaired electrons with parallel spins. The coupling type is Hund's case b), and each rotational level N is divided into three levels J {\displaystyle J} = N − 1 {\displaystyle N-1} , N {\displaystyle N} , N + 1 {\displaystyle N+1} .

  5. Electronic effect - Wikipedia

    en.wikipedia.org/wiki/Electronic_effect

    Electronic spin state at it simplest describes the number of unpaired electrons in a molecule. Most molecules including the proteins, carbohydrates, and lipids that make up the majority of life have no unpaired electrons even when charged. Such molecules are called singlet molecules, since their paired electrons have only one spin state.

  6. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    Shows location of unpaired electrons, bonded atoms, and bond angles. The bond angle for water is 104.5°. Valence shell electron pair repulsion ( VSEPR ) theory ( / ˈ v ɛ s p ər , v ə ˈ s ɛ p ər / VESP -ər , [ 1 ] : 410 və- SEP -ər [ 2 ] ) is a model used in chemistry to predict the geometry of individual molecules from the number of ...

  7. Radical disproportionation - Wikipedia

    en.wikipedia.org/wiki/Radical_disproportionation

    Radical disproportionation encompasses a group of reactions in organic chemistry in which two radicals react to form two different non-radical products. Radicals in chemistry are defined as reactive atoms or molecules that contain an unpaired electron or electrons in an open shell.

  8. Radical (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Radical_(chemistry)

    In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes.

  9. Dangling bond - Wikipedia

    en.wikipedia.org/wiki/Dangling_bond

    In the simplest case, that of a single bond, two atoms each contribute one unpaired electron, and the resulting pair of electrons is shared between them. Atoms that possess too few bonding partners to satisfy their valences and that possess unpaired electrons are termed "free radicals"; so, often, are molecules containing such atoms. When a ...