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Hydrogen sulfide is also a potent cellular toxin, blocking the cytochrome system and inhibiting cellular respiration. More water-soluble gases (e.g. chlorine, ammonia, sulfur dioxide, hydrogen chloride) dissolve in the upper airway and immediately cause mucous membrane irritation, which may alert people to the need to escape the exposure.
Hydrogen sulfide is a central participant in the sulfur cycle, the biogeochemical cycle of sulfur on Earth. [ 109 ] In the absence of oxygen , sulfur-reducing and sulfate-reducing bacteria derive energy from oxidizing hydrogen or organic molecules by reducing elemental sulfur or sulfate to hydrogen sulfide.
Initially, the suspected sources of the odors included SO 2, hydrogen sulfide (H 2 S), methylmercaptan, aldehydes, and other substances found to be leaking from the factories. [3] However, sulfur dioxide emitted from the combustion of high sulfur content oil has typically been attributed as the cause of the disease since the beginning.
Sulfur water (or sulphur water) is a condition where water is exposed to hydrogen sulfide gas, giving it a distinct "rotten egg" smell. This condition has different purposes in culture varying from health to implications for plumbing.
Under anaerobic conditions, sulfide can be oxidized to sulfur and then sulfate by Purple and Green sulfur bacteria. H 2 S → S 0 → SO 2− 4. Sulfur Oxidation. Sulfur can also be oxidized to sulfuric acid by chemolithotrophic bacteria, such as Thiobacillus and Acidithiobacillus. S 0 + 2O 2 → H 2 SO 4. Sulfur Reduction
It is a rare blood condition in which the β-pyrrole ring of the hemoglobin molecule has the ability to bind irreversibly to any substance containing a sulfur atom. [1] [2] When hydrogen sulfide (H 2 S) (or sulfide ions) and ferrous ions combine in the heme of hemoglobin, the blood is thus incapable of transporting oxygen to the tissues.
The important sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. [1]
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.