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Nitrification is the biological oxidation of ammonia to nitrate via the intermediary nitrite. Nitrification is an important step in the nitrogen cycle in soil. The process of complete nitrification may occur through separate organisms [1] or entirely within one organism, as in comammox bacteria. The transformation of ammonia to nitrite is ...
[12] [13] Complete nitrification, the conversion of ammonia to nitrate in a single step known as comammox, has an energy yield (∆G°′) of −349 kJ mol −1 NH 3, while the energy yields for the ammonia-oxidation and nitrite-oxidation steps of the observed two-step reaction are −275 kJ mol −1 NH 3, and −74 kJ mol −1 NO 2 − ...
The conversion of ammonium to nitrate is performed primarily by soil-living bacteria and other nitrifying bacteria. In the primary stage of nitrification, the oxidation of ammonium (NH + 4) is performed by bacteria such as the Nitrosomonas species, which converts ammonia to nitrites (NO − 2).
Additionally, with increasing NH 4 + accumulation in the soil, nitrification processes release hydrogen ions, which acidify the soil. NO 3 −, the product of nitrification, is highly mobile and can be leached from the soil, along with positively charged alkaline minerals such as calcium and magnesium. [4]
Both microbes play a significant role in the nitrification of soils. [1] [2] Nitrososphaera utilize ammonia from the environment to generate ATP by oxidizing ammonia (NH 3) into nitrite (NO 2 −). [11] Ammonia oxidation leads to the disaggregation of other chemical compounds, providing important nutrients for plant survival. [1]
Comammox (COMplete AMMonia OXidation) is the name attributed to an organism that can convert ammonia into nitrite and then into nitrate through the process of nitrification. [1] Nitrification has traditionally been thought to be a two-step process, where ammonia-oxidizing bacteria and archaea oxidize ammonia to nitrite and then nitrite ...
Denitrifying bacteria have been identified in over 50 genera with over 125 different species and are estimated to represent 10-15% of bacteria population in water, soil and sediment. [3] Denitrifying include for example several species of Pseudomonas, Alcaligenes, Bacillus and others. Pseudomonas stutzeri, a species of denitrifying bacteria
The process of nitrification is crucial for separating recycled production from production leading to export. Biologically metabolized nitrogen returns to the inorganic dissolved nitrogen pool in the form of ammonia. Microbe-mediated nitrification converts that ammonia into nitrate, which can subsequently be taken up by phytoplankton and recycled.