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Wulff construction. The surface free energy is shown in red, with in black normals to lines from the origin to .The inner envelope is the Wulff shape, shown in blue. The Wulff construction is a method to determine the equilibrium shape of a droplet or crystal of fixed volume inside a separate phase (usually its saturated solution or vapor).
The term "particle" in this context refers to gaseous particles only (atoms or molecules), and the system of particles is assumed to have reached thermodynamic equilibrium. [1] The energies of such particles follow what is known as Maxwell–Boltzmann statistics , and the statistical distribution of speeds is derived by equating particle ...
The Boltzmann distribution () / is an equilibrium distribution, and assuming grows sufficiently rapidly (that is, the potential well is deep enough to confine the particle), the Boltzmann distribution is the unique equilibrium.
The grand canonical partition function applies to a grand canonical ensemble, in which the system can exchange both heat and particles with the environment, at fixed temperature, volume, and chemical potential. Other types of partition functions can be defined for different circumstances; see partition function (mathematics) for generalizations.
In a state of dynamic equilibrium, and under the hypothesis of isothermal fluid, the particles are distributed according to the barometric distribution = (), where ρ − ρ o is the difference in density of particles separated by a height difference, of =, k B is the Boltzmann constant (the ratio of the universal gas constant, R, to the ...
Schematic of D2Q9 lattice vectors for 2D Lattice Boltzmann. Unlike CFD methods that solve the conservation equations of macroscopic properties (i.e., mass, momentum, and energy) numerically, LBM models the fluid consisting of fictive particles, and such particles perform consecutive propagation and collision processes over a discrete lattice.
In statistical mechanics, the grand canonical ensemble (also known as the macrocanonical ensemble) is the statistical ensemble that is used to represent the possible states of a mechanical system of particles that are in thermodynamic equilibrium (thermal and chemical) with a reservoir. [1]
The equilibrium conditions are shown as curves on a curved surface in 3D with areas for solid, liquid, and vapor phases and areas where solid and liquid, solid and vapor, or liquid and vapor coexist in equilibrium. A line on the surface called a triple line is where solid, liquid and vapor can all coexist in equilibrium. The critical point ...