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Commercial production of ethylene oxide dates back to 1914 when BASF built the first factory which used the chlorohydrin process (reaction of ethylene chlorohydrin with calcium hydroxide). The chlorohydrin process was unattractive for several reasons, including low efficiency and loss of valuable chlorine into calcium chloride . [ 64 ]
The reaction typically proceeds by blowing ethylene oxide through the alcohol at 180 °C and under 1-2 bar of pressure, with potassium hydroxide (KOH) serving as a catalyst. [5] The process is highly exothermic (ΔH = -92 kJ/mol of ethylene oxide reacted) and requires careful control to avoid a potentially disastrous thermal runaway. [5]
Ethylene is oxidized to produce ethylene oxide, a key raw material in the production of surfactants and detergents by ethoxylation. Ethylene oxide is also hydrolyzed to produce ethylene glycol , widely used as an automotive antifreeze as well as higher molecular weight glycols, glycol ethers , and polyethylene terephthalate .
Andrussow process: platinum (heterogeneous) hydrogen cyanide: basic chemicals, gold mining extractant ethylene: epoxidation: mixed Ag oxides (heterogeneous) ethylene oxide: basic chemicals, surfactants cyclohexane: K-A process: Co and Mn salts (homogeneous) cyclohexanol cyclohexanone: nylon precursor ethylene: Wacker process: Pd and Cu salts ...
The OMEGA process ("Only MEG Advantage") [1] is a chemical process discovered by the Shell Global Solutions company that is used to produce ethylene glycol from ethylene.This process comprises two steps, the controlled oxidation of ethylene to ethylene oxide, and the net hydrolysis of ethylene oxide to monoethylene glycol (MEG). [2]
The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde in the presence of palladium(II) chloride and copper(II) chloride as the catalyst. [1]
Polymerization of ethylene oxide is an exothermic process. Overheating or contaminating ethylene oxide with catalysts such as alkalis or metal oxides can lead to runaway polymerization, which can end in an explosion after a few hours. Polyethylene oxide, or high-molecular-weight polyethylene glycol, is synthesized by suspension polymerization.
The traditional manufacturing process calls for the reaction of ethylene oxide with acrylic acid in the presence of a metal catalyst. [4]