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Top to bottom: electrophilic addition to alkene, nucleophilic addition of nucleophile to carbonyl and free-radical addition of halide to alkene. Depending on the product structure, it could promptly react further to eject a leaving group to give the addition–elimination reaction sequence. Addition reactions are useful in analytic chemistry ...
The Kharasch addition is an organic reaction and a metal-catalysed free radical addition of CXCl 3 compounds (X = Cl, Br, H) to alkenes. [1] The reaction is used to append trichloromethyl or dichloromethyl groups to terminal alkenes. The method has attracted considerable interest, [2] but it is of limited value because of narrow substrate scope ...
The reaction follows Markovnikov's rule (the hydroxy group will always be added to the more substituted carbon). The oxymercuration part of the reaction involves anti addition of OH group but the demercuration part of the reaction involves free radical mechanism and is not stereospecific, i.e. H and OH may be syn or anti to each other. [2] [3] [4]
In organic chemistry, syn-and anti-addition are different ways in which substituent molecules can be added to an alkene (R 2 C=CR 2) or alkyne (RC≡CR).The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction.
The addition of the hydrogen ion to one carbon atom in the alkene creates a positive charge on the other carbon, forming a carbocation intermediate. The more substituted the carbocation, the more stable it is, due to induction and hyperconjugation. The major product of the addition reaction will be the one formed from the more stable intermediate.
Cyclization reactions, or intramolecular addition reactions, can be used to form cycloalkenes. These reactions primarily form cyclopentenones, a cycloalkene that contains two functional groups: the cyclopentene and a ketone group. [12] However, other cycloalkenes, such as Cyclooctatetraene, can be formed as a result of this reaction. [11]
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