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Polyester fibers have high tenacity and E-modulus as well as low water absorption and minimal shrinkage in comparison with other industrial fibers. Increasing the aromatic parts of polyesters increases their glass transition temperature, melting temperature, thermostability, chemical stability, and solvent resistance.
Polybenzimidazole (PBI, short for Poly-[2,2’-(m-phenylen)-5,5’-bisbenzimidazole]) fiber is a synthetic fiber with a very high melting point. It has exceptional thermal and chemical stability and does not readily ignite.
Dipole bonding is not as strong as hydrogen bonding, so a polyester's melting point and strength are lower than Kevlar's , but polyesters have greater flexibility. Polymers with non-polar units such as polyethylene interact only through weak Van der Waals forces. As a result, they typically have lower melting temperatures than other polymers.
This interferes with crystallization and lowers the polymer's melting temperature. In general, such PET is known as PETG or PET-G (polyethylene terephthalate glycol-modified). It is a clear amorphous thermoplastic that can be injection-molded, sheet-extruded or extruded as filament for 3D printing .
Polycaprolactone (PCL) is a synthetic, semi-crystalline, biodegradable polyester with a melting point of about 60 °C and a glass transition temperature of about −60 °C. [2] [3] The most common use of polycaprolactone is in the production of speciality polyurethanes.
Polyester resins are synthetic resins formed by the reaction of dibasic organic acids and polyhydric alcohols. Maleic anhydride is a commonly used raw material with diacid functionality in unsaturated polyester resins. [1] Unsaturated polyester resins are used in sheet moulding compound, bulk moulding compound and the toner of laser printers.
Polyglycolide has a glass transition temperature between 35 and 40 °C and its melting point is reported to be in the range of 225 to 230 °C. PGA also exhibits an elevated degree of crystallinity, around 45–55%, thus resulting in insolubility in water. [2]
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa.