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Thiophene-2-carboxaldehyde is an organosulfur compound with the formula C 4 H 3 SCHO. It is one of two isomeric thiophenecarboxaldehydes. It is a colorless liquid that often appears amber after storage. It is versatile precursor to many drugs including eprosartan, Azosemide, and Teniposide.
Thiophene-2-carboxylic acid is an organic compound with the formula SC 4 H 3 CO 2 H. It is one of two mono carboxylic acids of thiophene , the other being thiophene-3-carboxylic acid. [ 1 ] Copper(I) thiophene-2-carboxylate is a catalyst for Ullmann coupling reactions .
Halogens give initially 2-halo derivatives followed by 2,5-dihalothiophenes; perhalogenation is easily accomplished to give C 4 X 4 S (X = Cl, Br, I). [20] Thiophene brominates 10 7 times faster than does benzene. Acetylation occurs readily to give 2-acetylthiophene, precursor to thiophene-2-carboxylic acid and thiophene-2-acetic acid. [9]
Copper(I) thiophene-2-carboxylate or CuTC is a coordination complex derived from copper and thiophene-2-carboxylic acid. It is used as a reagent to promote the Ullmann reaction between aryl halides. [3] CuTC catalyzed Ullmann coupling
2-Acetylthiophene is an organosulfur compound with the formula CH 3 C(O)C 4 H 3 S. A yellow liquid, it is the more useful of the two isomers of acetylthiophene. It is of commercial interest as a precursor to both thiophene-2-carboxylic acid and thiophene-2-acetic acid. [2]
2-Methylthiophene is an organosulfur compound with the formula CH 3 C 4 H 3 S. It is a colorless, flammable liquid. It is a colorless, flammable liquid. It can be produced by Wolff-Kishner reduction of thiophene-2-carboxaldehyde . [ 1 ]
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The Fiesselmann thiophene synthesis is a name reaction in organic chemistry that allows for the generation of 3-hydroxy-2-thiophenecarboxylic acid derivatives from α,β-acetylenic esters with thioglycolic acid and its derivatives under the presence of a base. The reaction was developed by Hans Fiesselmann in the 1950s.