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Fluorobenzaldehyde can be used as a synthetic intermediate because the fluorine can be replaced via oxidation reaction. [1] Due to the aldehyde group, the fluorobenzaldehydes can be used to make a variety of schiff base compounds through a condensation reaction , some of which have antimicrobial properties.
2-Chloro-6-fluorobenzaldehyde is prepared by oxidation of 2-chloro-6-fluorotolulene by chromyl chloride. [3] It reacts with sodium hydroxide to give a mixture of 2-chloro-6-fluorobenzene and 6-chlorosalicaldehyde. [4] 2-Chloro-6-fluorobenzaldehyde is used in the production of the antiseptics dicloxacillin and flucloxacillin.
The inductive and resonance properties compete with each other but the resonance effect dominates for purposes of directing the sites of reactivity. For nitration, for example, fluorine directs strongly to the para position because the ortho position is inductively deactivated (86% para, 13% ortho, 0.6% meta).
PhF behaves rather differently from other halobenzene derivatives owing to the pi-donor properties of fluoride. For example, the para position is more activated than benzene toward electrophiles. For this reason, it can be converted to 1-bromo-4-fluorobenzene with relatively high efficiency. [3]
2-chloro-6-fluorobenzaldehyde: 387-45-1 C 7 H 4 ClNO 2: chloroxazone: 95-25-0 C 7 H 4 CrO 3 S: thiophene chromium tricarbonyl: 12078-15-8 C 7 H 4 CrO 3 Se: selenophene chromium tricarbonyl: 12078-16-9 C 7 H 4 CrO 3 Te: tellurophene chromium tricarbonyl: 39015-36-6 C 7 H 4 MnNO 3: azacymantrene: 32761-36-7 C 7 H 4 O 3 S: tioxolone: 4991-65-5 C 7 ...
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For example, the three isomers of xylene CH 3 C 6 H 4 CH 3, commonly the ortho-, meta-, and para-forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4-dimethylbenzene. The cyclic structures can also be treated as functional groups themselves, in which case they take the prefix "cyclo alkyl -" (e.g. "cyclohexyl-") or for benzene, "phenyl-".
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