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A superabsorbent polymer (SAP) (also called slush powder) is a water-absorbing hydrophilic homopolymers or copolymers [1] that can absorb and retain extremely large amounts of a liquid relative to its own mass. [2] Water-absorbing polymers, which are classified as hydrogels when mixed, [3] absorb aqueous solutions through hydrogen bonding with ...
In polymer chemistry, suspension polymerization is a heterogeneous radical polymerization process that uses mechanical agitation to mix a monomer or mixture of monomers in a liquid phase, such as water, while the monomers polymerize, forming spheres of polymer. [2] The monomer droplets (size of the order 10-1000 μm) are suspended in the liquid ...
The reaction results in a polymer which is also soluble in the chosen solvent. Heat released by the reaction is absorbed by the solvent, reducing the reaction rate. Moreover, the viscosity of the reaction mixture is reduced, preventing autoacceleration at high monomer concentrations. A decrease in viscosity of the reaction mixture by dilution ...
Super-absorbent polymers (SAP) similar to sodium polyacrylate were developed in the 1960s by the U.S. Department of Agriculture. [3] Before the development of these substances, the best water absorbing materials were cellulosic or fiber-based like tissue paper, sponge, cotton, or fluff pulp.
A small amount of superabsorbent polymer material is taken (0.1g) and it is placed in the beaker. 100 ml of deionized water is poured into the beaker. After 20 min the swollen polymer was separated by using [filter paper] By weighing the polymer, one can find the swollen capacity of the SAP material. [3]
In materials science, liquefaction [1] is a process that generates a liquid from a solid or a gas [2] or that generates a non-liquid phase which behaves in accordance with fluid dynamics. [3] It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to ...
The liquid molecules are more attracted to other liquid molecules as compared to the polymer surface. Because the polymer surfaces are solid surfaces, surface tension cannot be measured in a traditional way such as using a Wilhelmy plate. Instead, contact angles can be used to indirectly estimate the surface tension of polymer surfaces. [3]
In a liquid-liquid interface with monomer dissolved in one phase, polymerization occurs on only one side of the interface, whereas in liquid-liquid interfaces with monomer dissolved in both phases, polymerization occurs on both sides. [2] An interfacial polymerization reaction may proceed either stirred or unstirred.