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Liquid junction potential (shortly LJP) occurs when two solutions of electrolytes of different concentrations are in contact with each other. The more concentrated solution will have a tendency to diffuse into the comparatively less concentrated one.
The practical importance of high (i.e. close to 1) transference numbers of the charge-shuttling ion (i.e. Li+ in lithium-ion batteries) is related to the fact, that in single-ion devices (such as lithium-ion batteries) electrolytes with the transfer number of the ion near 1, concentration gradients do not develop. A constant electrolyte ...
The equivalent circuit model (ECM) is a common lumped-element model for Lithium-ion battery cells. [ 1 ] [ 2 ] [ 3 ] The ECM simulates the terminal voltage dynamics of a Li-ion cell through an equivalent electrical network composed passive elements, such as resistors and capacitors , and a voltage generator .
Electrolyte imbalance, or water-electrolyte imbalance, is an abnormality in the concentration of electrolytes in the body. Electrolytes play a vital role in maintaining homeostasis in the body. They help to regulate heart and neurological function, fluid balance , oxygen delivery , acid–base balance and much more.
The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model, which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean activity coefficients for ions in dilute solution.
The first term on the right-hand side is the Debye–Hückel term, with a constant, A, and the ionic strength I. β is an interaction coefficient and b the molality of the electrolyte. As the concentration decreases so the second term becomes less important until, at very low concentrations, the Debye-Hückel equation gives a satisfactory ...
Pictorial representation of two interacting charged plates across an electrolyte solution. The distance between the plates is abbreviated by h. The most popular model to describe the electrical double layer is the Poisson-Boltzmann (PB) model. This model can be equally used to evaluate double layer forces.
Osmoregulation is the active regulation of the osmotic pressure of an organism's body fluids, detected by osmoreceptors, to maintain the homeostasis of the organism's water content; that is, it maintains the fluid balance and the concentration of electrolytes (salts in solution which in this case is represented by body fluid) to keep the body fluids from becoming too diluted or concentrated.