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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
This page provides supplementary chemical data on boric acid. Thermodynamic properties. Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ?
A broader definition of acid dissociation includes hydrolysis, in which protons are produced by the splitting of water molecules. For example, boric acid (B(OH) 3) produces H 3 O + as if it were a proton donor, [11] but it has been confirmed by Raman spectroscopy that this is due to the hydrolysis equilibrium: [12]
For example, acetic acid is a weak acid which has a = 1.75 x 10 −5. Its conjugate base is the acetate ion with K b = 10 −14 /K a = 5.7 x 10 −10 (from the relationship K a × K b = 10 −14), which certainly does not correspond to a strong base. The conjugate of a weak acid is often a weak base and vice versa.
The addition of mannitol to an initially neutral solution containing boric acid or borates lowers the pH enough for the be titrated by a strong base as NaOH, including with an automated a potentiometric titrator. This is a reliable method to assay the amount of borate content present in the solution. [3]
The simplest hydroxide of boron B(OH) 3, known as boric acid, is an acid. Unlike the hydroxides of the alkali and alkaline earth hydroxides, it does not dissociate in aqueous solution. Instead, it reacts with water molecules acting as a Lewis acid, releasing protons. B(OH) 3 + H 2 O ⇌ B(OH) − 4 + H +
H 2 O is a base because it accepts a proton from CH 3 COOH and becomes its conjugate acid, the hydronium ion, (H 3 O +). [9] The reverse of an acid–base reaction is also an acid–base reaction, between the conjugate acid of the base in the first reaction and the conjugate base of the acid.
The strength of Lewis basicity correlates with the pK a of the parent acid: acids with high pK a 's give good Lewis bases. As usual, a weaker acid has a stronger conjugate base . Examples of Lewis bases based on the general definition of electron pair donor include:
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