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However, good approximations can be made for gases in many states using simpler methods outlined below. For many solids composed of relatively heavy atoms (atomic number > iron), at non-cryogenic temperatures, the heat capacity at room temperature approaches 3R = 24.94 joules per kelvin per mole of atoms (Dulong–Petit law, R is the gas constant).
Most writers use it as a synonym for heat capacity, the ability of a body to store thermal energy. It is typically referred to by the symbol C th, and its SI unit is J/K or J/°C (which are equivalent). However: Christoph Reinhart at MIT describes thermal mass as its volume times its volumetric heat capacity. [1]
The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found by dividing the heat capacity of an object by its mass. Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity.
The SI unit of volumetric heat capacity is joule per kelvin per cubic meter, J⋅K −1 ⋅m −3. The volumetric heat capacity can also be expressed as the specific heat capacity (heat capacity per unit of mass, in J⋅K −1 ⋅kg −1) times the density of the substance (in kg/L, or g/mL). [1] It is defined to serve as an intensive property.
where is the specific heat capacity (at constant pressure, in case of a gas) and is the density (mass per unit volume) of the material. This derivation assumes that the material has constant mass density and heat capacity through space as well as time.
The CLF is the cooling load at a given time compared to the heat gain from earlier in the day. [1] [5] The SC, or shading coefficient, is used widely in the evaluation of heat gain through glass and windows. [1] [5] Finally, the SCL, or solar cooling load factor, accounts for the variables associated with solar heat load.
The heat capacity depends on how the external variables of the system are changed when the heat is supplied. If the only external variable of the system is the volume, then we can write: d S = ( ∂ S ∂ T ) V d T + ( ∂ S ∂ V ) T d V {\displaystyle dS=\left({\frac {\partial S}{\partial T}}\right)_{V}dT+\left({\frac {\partial S}{\partial V ...
is the isobaric heat capacity of the fluid is 0.4 for heating (wall hotter than the bulk fluid) and 0.33 for cooling (wall cooler than the bulk fluid). [11] The fluid properties necessary for the application of this equation are evaluated at the bulk temperature thus avoiding iteration.