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A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). [1] Examples are organolithium compounds and triethylborane.
It is a colorless, pyrophoric gas with a sharp, repulsive, pungent smell, somewhat similar to that of acetic acid. [6] Silane is of practical interest as a precursor to elemental silicon . Silanes with alkyl groups are effective water repellents for mineral surfaces such as concrete and masonry.
Germane is a highly flammable, potentially pyrophoric, [11] and a highly toxic gas. In 1970, the American Conference of Governmental Industrial Hygienists (ACGIH) published the latest changes and set the occupational exposure threshold limit value at 0.2 ppm for an 8-hour time weighted average. [ 12 ]
Notable examples include alkali metals, lithium through caesium, and alkaline earth metals, magnesium through barium. Some water-reactive substances are also pyrophoric, like organometallics and sulfuric acid. The use of acid-resistant gloves and face shield is recommended for safe handling; fume hoods are another effective control of such ...
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately. Blue type items have an article available by ...
Trimethylborane spontaneously ignites in air if the concentration is high enough. It burns with a green flame producing soot. [11] Slower oxidation with oxygen in a solvent or in the gas phase can produce dimethyltrioxadiboralane, which contains a ring of two boron and three oxygen atoms.
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride.Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P 2 H 4).
Diborane(6), commonly known as diborane, is the chemical compound with the formula B 2 H 6.It is a highly toxic, colorless, and pyrophoric gas with a repulsively sweet odor. . Given its simple formula, borane is a fundamental boron compou