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In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid.It is directly related to the concentration gradient of the permeate, a material's intrinsic permeability, and the materials' mass diffusivity. [1]
The term was coined by William Thomson, 1st Baron Kelvin in 1872, [1] and used alongside permittivity by Oliver Heaviside in 1885. The reciprocal of permeability is magnetic reluctivity. In SI units, permeability is measured in henries per meter (H/m), or equivalently in newtons per ampere squared (N/A 2).
To account for the internal energy of the open system, this requires energy transfer terms in addition to those for heat and work. It also leads to the idea of the chemical potential. A wall selectively permeable only to a pure substance can put the system in diffusive contact with a reservoir of that pure substance in the surroundings.
For example, for a wall permeable only to heat, the rates of diffusion of internal energy as heat between the two systems are equal and opposite. An adiabatic wall between the two systems is 'permeable' only to energy transferred as work; at mechanical equilibrium the rates of transfer of energy as work between them are equal and opposite.
The concept of permeability is of importance in determining the flow characteristics of hydrocarbons in oil and gas reservoirs, [4] and of groundwater in aquifers. [5]For a rock to be considered as an exploitable hydrocarbon reservoir without stimulation, its permeability must be greater than approximately 100 md (depending on the nature of the hydrocarbon – gas reservoirs with lower ...
Electrochemical energy is one of the many interchangeable forms of potential energy through which energy may be conserved. It appears in electroanalytical chemistry and has industrial applications such as batteries and fuel cells. In biology, electrochemical gradients allow cells to control the direction ions move across membranes.
The darcy is referenced to a mixture of unit systems. A medium with a permeability of 1 darcy permits a flow of 1 cm 3 /s of a fluid with viscosity 1 cP (1 mPa·s) under a pressure gradient of 1 atm/cm acting across an area of 1 cm 2.
Chemiosmosis is the movement of ions across a semipermeable membrane bound structure, down their electrochemical gradient.An important example is the formation of adenosine triphosphate (ATP) by the movement of hydrogen ions (H +) across a membrane during cellular respiration or photosynthesis.