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Sulfuryl chloride is not found in nature, as can be inferred from its rapid hydrolysis. Sulfuryl chloride is commonly confused with thionyl chloride, SOCl 2. The properties of these two sulfur oxychlorides are quite different: sulfuryl chloride is a source of chlorine whereas thionyl chloride is a source of chloride ions.
Further heating (180 °C) of potassium fluorosulfite with the sulfuryl chloride fluoride gives sulfuryl fluoride. KSO 2 F + SO 2 ClF → SO 2 F 2 + KCl + SO 2. Alternatively, sulfuryl chloride fluoride can be prepared without using gases as starting materials by treating sulfuryl chloride with ammonium fluoride or potassium fluoride in ...
The structure of the sulfuryl group In inorganic chemistry , the sulfuryl group is a functional group consisting of a sulfur atom covalently bound to two oxygen atoms ( S(=O) 2 X 2 ). It occurs in compounds such as sulfuryl chloride , SO 2 Cl 2 and sulfuryl fluoride , SO 2 F 2 .
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4-Toluenesulfonyl chloride (p-toluenesulfonyl chloride, toluene-p-sulfonyl chloride) is an organic compound with the formula CH 3 C 6 H 4 SO 2 Cl. This white, malodorous solid is a reagent widely used in organic synthesis. [2] Abbreviated TsCl or TosCl, it is a derivative of toluene and contains a sulfonyl chloride (−SO 2 Cl) functional group.
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Methylphosphonyl dichloride is produced by oxidation of methyldichlorophosphine, with sulfuryl chloride: [3] CH 3 PCl 2 + SO 2 Cl 2 → CH 3 P(O)Cl 2 + SOCl 2. It can also be produced from a range of methylphosphonates (e.g. dimethyl methylphosphonate) via chlorination with thionyl chloride. Various amines catalyse this process. [4]
Acetyl chloride was first prepared in 1852 by French chemist Charles Gerhardt by treating potassium acetate with phosphoryl chloride. [4]Acetyl chloride is produced in the laboratory by the reaction of acetic acid with chlorodehydrating agents such as phosphorus trichloride (PCl 3), phosphorus pentachloride (PCl 5), sulfuryl chloride (SO 2 Cl 2), phosgene, or thionyl chloride (SOCl 2).