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This yields Kirchhoff's law: α λ = ε λ {\displaystyle \alpha _{\lambda }=\varepsilon _{\lambda }} By a similar, but more complicated argument, it can be shown that, since black-body radiation is equal in every direction (isotropic), the emissivity and the absorptivity, if they happen to be dependent on direction, must again be equal for any ...
Spectroscope of Kirchhoff and Bunsen. The systematic attribution of spectra to chemical elements began in the 1860s with the work of German physicists Robert Bunsen and Gustav Kirchhoff, [30] who found that Fraunhofer lines correspond to emission spectral lines observed in laboratory light sources. This laid way for spectrochemical analysis in ...
Kirchhoff's laws, named after Gustav Kirchhoff, may refer to: Kirchhoff's circuit laws in electrical engineering; Kirchhoff's law of thermal radiation; Kirchhoff equations in fluid dynamics; Kirchhoff's three laws of spectroscopy; Kirchhoff's law of thermochemistry; Kirchhoff's theorem about the number of spanning trees in a graph
Kirchhoff's 1860 paper did not mention the second law of thermodynamics, and of course did not mention the concept of entropy which had not at that time been established. In a more considered account in a book in 1862, Kirchhoff mentioned the connection of his law with Carnot's principle , which is a form of the second law.
It was not until 33 years after his passing that Gustav Kirchhoff established that each element and compound has its unique spectrum and that by studying the spectrum of an unknown source, one could determine its chemical compositions, and with these advancements, spectroscopy became a truly scientific method of analyzing the structures of ...
Gustav Robert Kirchhoff (German: [ˈgʊs.taf ˈkɪʁçhɔf]; 12 March 1824 – 17 October 1887) was a German physicist, chemist and mathematican who contributed to the fundamental understanding of electrical circuits, spectroscopy and the emission of black-body radiation by heated objects.
A wide variety of absorption band and line shapes exist, and the analysis of the band or line shape can be used to determine information about the system that causes it. In many cases it is convenient to assume that a narrow spectral line is a Lorentzian or Gaussian , depending respectively on the decay mechanism or temperature effects like ...
In atomic, molecular, and optical physics, the Einstein coefficients are quantities describing the probability of absorption or emission of a photon by an atom or molecule. [1] The Einstein A coefficients are related to the rate of spontaneous emission of light, and the Einstein B coefficients are related to the absorption and stimulated ...