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In one group, including M 2 UO 4 (M=Li, Na, K) and MUO 4 (M=Ca, Sr) there are six additional oxygen atoms. Taking calcium uranate, CaUO 4 , as an example, the six oxygen atoms are arranged as a flattened octahedron , flattened along the 3-fold symmetry axis of the octahedron which also runs through the O-U-O axis (local point group D 3d at the ...
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The uranyl ion is always associated with other ligands. The most common arrangement is for the so-called equatorial ligands to lie in a plane perpendicular to the O–U–O line and passing through the uranium atom. With four ligands, as in [UO 2 Cl 4] 2−, the uranium has a distorted octahedral environment. In many cases more than four ...
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2 + 4 HF → UF 4 + 2 H 2 O (500 °C, endothermic) UF 4 + F 2 → UF 6 (350 °C, endothermic) The resulting UF 6, a white solid, is highly reactive (by fluorination), easily sublimes (emitting a vapor that behaves as a nearly ideal gas), and is the most volatile compound of uranium known to exist. [6] One method of preparing uranium ...
Uranyl nitrate is a water-soluble yellow uranium salt with the formula UO 2 (NO 3) 2 · n H 2 O.The hexa-, tri-, and dihydrates are known. [3] The compound is mainly of interest because it is an intermediate in the preparation of nuclear fuels.
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2 O 2− 7, this is not necessarily the case. It can also be called diammonium diuranium heptaoxide. The structure was theorized to be similar to that of uranium trioxide dihydrate. [1] [2] Recent literature has shown that the structure more closely resembles the mineral metaschoepite, the partially dehydrated form of schoepite. [3]
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