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[a] While processes in isolated systems are never reversible, [3] cyclical processes can be reversible or irreversible. [4] Reversible processes are hypothetical or idealized but central to the second law of thermodynamics. [3] Melting or freezing of ice in water is an example of a realistic process that is nearly reversible.
A and B can react to form C and D or, in the reverse reaction, C and D can react to form A and B. This is distinct from a reversible process in thermodynamics. Weak acids and bases undergo reversible reactions. For example, carbonic acid: H 2 CO 3 (l) + H 2 O (l) ⇌ HCO 3 − (aq) + H 3 O + (aq).
Example of a real system modelled by an idealized process: PV and TS diagrams of a Brayton cycle mapped to actual processes of a gas turbine engine Thermodynamic cycles may be used to model real devices and systems, typically by making a series of assumptions to reduce the problem to a more manageable form. [ 2 ]
For any irreversible process, since entropy is a state function, we can always connect the initial and terminal states with an imaginary reversible process and integrating on that path to calculate the difference in entropy. Now reverse the reversible process and combine it with the said irreversible process.
For reversible processes, an isentropic transformation is carried out by thermally "insulating" the system from its surroundings. Temperature is the thermodynamic conjugate variable to entropy, thus the conjugate process would be an isothermal process , in which the system is thermally "connected" to a constant-temperature heat bath.
Reversible process (thermodynamics), a process or cycle such that the net change at each stage in the combined entropy of the system and its surroundings is zero; Reversible reaction, a chemical reaction for which the position of the chemical equilibrium is very sensitive to the imposed physical conditions; so the reaction can be made to run ...
An isentropic process is customarily defined as an idealized quasi-static reversible adiabatic process, of transfer of energy as work. Otherwise, for a constant-entropy process, if work is done irreversibly, heat transfer is necessary, so that the process is not adiabatic, and an accurate artificial control mechanism is necessary; such is ...
Reversible-addition-fragmentation chain-transfer polymerization (RAFT polymerization, RAFT): Degenerate-transfer radical polymerization in which chain activation and chain deactivation involve a degenerative chain-transfer process which occurs by a two-step addition-fragmentation mechanism. Note 1: Examples of RAFT agents include certain ...